Sodium polyacrylate
Sodium polyacrylate is a widely used ingredient in cosmetics, personal care, and skincare formulations. Depending on its function, it may serve as a moisturizer, preservative, emulsifier, or active ingredient to enhance the overall effectiveness and performance of a product.
Sodium polyacrylate (ACR, ASAP, or PAAS), also known as waterlock, is a sodium salt of polyacrylic acid with the chemical formula [−CH2−CH(CO2Na)−]n and has broad applications in consumer products. This super-absorbent polymer (SAP) has the ability to absorb 100 to 1000 times its mass in water. Sodium polyacrylate is an anionic polyelectrolyte with negatively charged carboxylic groups in the main chain. It is a polymer made up of chains of acrylate compounds. It contains sodium, which gives it the ability to absorb large amounts of water. When dissolved in water, it forms a thick and transparent solution due to the ionic interactions of the molecules. Sodium polyacrylate has many favorable mechanical properties. Some of these advantages include good mechanical stability, high heat resistance, and strong hydration.
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| Names | |
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| IUPAC name
Poly(sodium prop-2-enoate)
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| Identifiers | |
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| ECHA InfoCard | 100.118.171 |
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| UNII |
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CompTox Dashboard (EPA)
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| Properties | |
| (C3H3NaO2)n | |
| Molar mass | Variable |
| Density | 1.22 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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While sodium neutralized polyacrylic acids are the most common form used in industry, there are also other salts available including potassium, lithium and ammonium. The origins of super-absorbent polymer chemistry trace back to the early 1960s when the U.S. Department of Agriculture (USDA) developed the first super-absorbent polymer materials.
